A spin crossover ferrous complex with ordered magnetic ferric anions.
نویسندگان
چکیده
The first tetrahaloferrate spin crossover compound, [Fe(Metz)(6)](FeBr(4))(2) (Metz = 1-methyltetrazole), is reported. The FeBr(4)(-) ions form ferromagnetically coupled 1D stacks and exhibit an antiferromagnetic order at 2.2 K, which coexists with the gradual spin crossover centred at 165 K.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 61 شماره
صفحات -
تاریخ انتشار 2012